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Hydroperoxo complexes oxidation catalysts

Solid catalysts may also be used for reactions implying oxidants differ by dioxygen. The most popular case is that of titanium-silicalite catalysts for oxidation with hydrogen peroxide. The active species in the presence of water has been characterised to be a side-on peroxo complex characterised by a Raman-detected 0-0 stretching at 618 cm Upon drying, this species converts into a hydroperoxo species characterised using IR by an 0-0 stretching at 837 cm and a broad OH band at 3400 cm ... [Pg.459]

See other pages where Hydroperoxo complexes oxidation catalysts is mentioned: [Pg.675]    [Pg.50]    [Pg.146]    [Pg.199]    [Pg.50]    [Pg.146]    [Pg.192]    [Pg.659]    [Pg.683]    [Pg.26]    [Pg.464]    [Pg.282]    [Pg.638]    [Pg.11]    [Pg.167]    [Pg.698]   
See also in sourсe #XX -- [ Pg.347 , Pg.348 , Pg.349 ]

See also in sourсe #XX -- [ Pg.347 , Pg.348 , Pg.349 ]

See also in sourсe #XX -- [ Pg.6 , Pg.347 , Pg.348 , Pg.349 ]



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Hydroperoxo

Hydroperoxo complexes

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