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Hydromagnesiation olefins

COOPER-FINKBEINER Hydromagnesiation Ti catalyzed formation of Grignard reagents from olefins or acetylenes. [Pg.69]

Table 3.3 displays a survey of the hydromagne-siation of various olefins with Grignard reagents. Like the aforementioned hydromagnesiation with inorganic MgHh, terminal olefins arc the only-acceptable substrates in this reaction, and give... [Pg.74]

COOPER - FINKBEINER Hydromagnesiation Ti catalyzed reaction ot Grignard reagents with olefins or acetylenes... [Pg.271]

Hydromagnesiation of a terminal olefin followed by the nickel-catalyzed vinylation with excess vinyl bromide provides a one-pot method of two-carbon homologation of the parent olefin as shown in eq. (3.22) [37],... [Pg.43]

From a synthesis perspective, quick and easy access to chemical space via simple procedures is extremely useful. Olefin hydromagnesiation reactions provide rapid, in situ, substrate diversification facilitated by the formation of a reactive intermediate Grignard species. ... [Pg.357]

See other pages where Hydromagnesiation olefins is mentioned: [Pg.124]    [Pg.124]    [Pg.109]    [Pg.110]    [Pg.137]    [Pg.229]    [Pg.34]    [Pg.74]    [Pg.82]    [Pg.96]    [Pg.102]    [Pg.39]    [Pg.39]    [Pg.39]    [Pg.42]    [Pg.43]    [Pg.46]    [Pg.47]    [Pg.54]    [Pg.57]    [Pg.254]    [Pg.254]    [Pg.259]    [Pg.266]    [Pg.267]    [Pg.22]   
See also in sourсe #XX -- [ Pg.66 , Pg.71 , Pg.74 ]



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Hydromagnesiation

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