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Hydrogen exchange sequence effect

The kinetics of hydrogenation transfer is covered by the use of an exchange superoperator assuming a pseudo first-order reaction. Thereby, competing hydrogenations of the substrate to more than one product can also be accommodated. In addition, the consequences of relaxation effects or NOEs can be included into the simulations if desired. Furthermore, it is possible to simulate the consequences of different types of pulse sequences, such as PH-INEPT or INEPT+, which have previously been developed for the transfer of polarization from the parahydrogen-derived protons to heteronuclei such as 13C or 15N. The... [Pg.341]


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See also in sourсe #XX -- [ Pg.8 ]




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