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Hydrogen chloride radicals from homolytic cleavage

The photoreduction of 2- and 3-chloroanisole in alcoholic solvents has been studied and is considered to be best accounted for by invoking methoxyphenyl radicals which abstract hydrogen atoms from the solvent378.4-Chloroanisole probably reacts partly via a homolytic cleavage, but in view of the results of quenching and sensitization experiments, another pathway consists of electron transfer from the solvent (ROH) to excited aryl halide, followed by dissociation of the radical anion into chloride ion and aryl radical. [Pg.907]

See other pages where Hydrogen chloride radicals from homolytic cleavage is mentioned: [Pg.47]    [Pg.208]    [Pg.208]    [Pg.464]    [Pg.47]    [Pg.208]    [Pg.47]    [Pg.215]    [Pg.67]    [Pg.7]    [Pg.309]    [Pg.1529]    [Pg.1529]    [Pg.242]    [Pg.151]    [Pg.65]   
See also in sourсe #XX -- [ Pg.1019 ]

See also in sourсe #XX -- [ Pg.1019 ]

See also in sourсe #XX -- [ Pg.1019 ]



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Homolytic

Homolytic cleavage

Homolytic cleavage-radical

Radical chloride

Radical cleavage

Radicals from

Radicals homolytic

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