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Hydrogen bromide to alkynes

A number of the photoaddition reactions of alkynes are not reactions of the alkyne excited state but involve the formation of free radicals by photocleavage of the other compound. The photochemical a/i//-Markownikoff addition of hydrogen bromide to alkynes (equation 35) under conditions where the ionic addition is very slow is an example of this -. [Pg.19]

Anti-Markovnikov addition of hydrogen bromide to alkynes occurs when peroxides are present in the reaction mixture. These reactions take place through a free-radical mechanism (Section 10.10) ... [Pg.375]


See also in sourсe #XX -- [ Pg.377 , Pg.379 , Pg.385 ]

See also in sourсe #XX -- [ Pg.377 , Pg.379 , Pg.385 ]

See also in sourсe #XX -- [ Pg.377 , Pg.379 , Pg.385 ]

See also in sourсe #XX -- [ Pg.353 , Pg.354 , Pg.361 ]




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Alkynes bromide

Alkynes hydrogenation

Bromides hydrogenation

Hydrogen bromid

Hydrogen bromide

Hydrogen bromide alkynes

To alkynes

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