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Hydroesterification, Hydroamidation, and Hydroacylation

The hydroesterification of alkenes is a versatile method for obtaining carboxylic esters from alkene, CO, and alcohol (Eq. 11.13) [45, 46]. [Pg.282]

Ethylene reacts with methanol with the Ru(CO)3(PCy3)2 catalyst even in the absence of CO to give methyl propionate (Eq. 11.14). [Pg.282]

Keim and coworkers examined the mechanism of this reaction using CHsOH and propylene. Methyl butyrate was obtained as a product, and C was found to be incorporated into both the carbonyl carbon and the methoxy group (Eq. 11.15) [47]. [Pg.282]

This result shows that the product is obtained upon the decomposition of methanol to CO and hydrogen (Eq. 11.16). [Pg.283]

The hydroesterification of allenes with alcohol and CO, when catalyzed by ruthenium complexes, gives acrylates [48, 49]. In the presence of amines, acrylamides are formed in high yields (Eq. 11.17). [Pg.283]


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Hydroesterification

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