Hydrodenitrogenation organometallic modeling

P.R. Raithby (eds), vol 2, Wiley-VCH, Weinheim, 1999, 741 (b) R.A. Sanchez-Delgado, Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions, Kluwar Academic Publishers, Dordrecht, 2002. 

R.A. Sanchez-Delgado, Organometallic Modeling of the Hydrodesuljurization and Hydrodenitrogenation Reactions. Kluwer, Dordrecht, 2002. 

Scheme 11 Desulfurization of thiols on Co-Mo-S clusters. Reproduced from Organometallic modeling of the hydrodesulfurization and hydrodenitrogenation, by R. A. Sanchez-Delgado in Catalysis by Metal Complexes] B. R. James and P. W. N. M. van Leeuwen, Eds. Kluwer Academic Publishers Dordrecht, Vol. 24, p. 126 (2002). With kind permission of Springer Science and Business Media.

A. Hydrodesulfurization and hydrodenitrogenation catalysis. The supported metal sulfides used as catalysts for hydroprocessing reactions have been characterized by many techniques, but the nature of the catalytically active sites is still a matter of controversy which makes it difficult to understand the mechanisms, and relevant organometallic models need to be developed. 

Weller KJ, Filippov I, Brig PM, Wigley DE. Pyridine degradation intermediates as models for hydrodenitrogenation catalysis preparation and properties of a metal-lapyridine complex. Organometallics. 1998 17 322-329. 

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