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In the hydroalumination of cyclic olefins with i-Bu2AlH the cis-addition in donor solvents is kinetically controlled . For indenes, polar effects are noticable, whereas steric effects are most important for 1-substituted acenaphtenes . The regiochemistry of the addition is controlled by steric effects except for trimethylsilyl substituents . The... [Pg.210]

See other pages where Hydroalumination substituent control, regiochemistry is mentioned: [Pg.275] [Pg.92]

See also in sourсe #XX -- [ Pg.750 ]

See also in sourсe #XX -- [ Pg.8 , Pg.750 ]

See also in sourсe #XX -- [ Pg.8 , Pg.750 ]