Ozone hydride abstraction

Abstraction of hydride by ozone results in an intimate ion pair which was originally thought to collapse exclusively to the covalent hydrotrioxide,... [Pg.587]

Careful investigation of reaction of ozone with C-H compounds (including alkanes) showed that a hydride abstraction and the concerted insertion of ozone into a C-H bond are most consistent with the kinetic data [40a] (see also [40b]). Table II. 10 contains the relative reactivities of some alkanes toward ozone as well as three radical species [40a]. [Pg.57]

The oxidation of acetals to esters (78) may also involve hydride abstraction by the soft positive pole of the ozone molecule the hard negative oxygen end occupies the site vacated by the hydride. [Pg.100]

The analysis of published data on reactions of ozone with low molecular hydrocarbons shows that double bonds react with ozone more quickly than saturated bonds (12). Ozone reacts with saturated hydrocarbons in reactions in which hydrogen abstraction s followed by re-hydridization of the carbon atom form sp to sp state (43,44) ... [Pg.196]

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