Hydrazine intercalation

Changes in the vibrational modes of the adsorbent, however, reflect only those changes which occur to the substrate they do not provide direct insight into the structure and bonding of the adsorbed species. In order to examine the influence of the surface on the intercalated species, the vibrational modes of the adsorbate must be obtained. In a previous dispersive-IR absorption study of the kaolinite-hydrazine intercalate, Ledoux and White (17) observed that the ISu hydroxyl groups of... 

Figure 4. FT-IR (A,B) and Raman (C,D) spectra of non-intercalated kaolinite (top spectra), and of kaolinite-hydrazine intercalates in the 3600 to 3725 cm-1 region (bottom spectra). Spectra were obtained at 298 K and 1 atm. pressure.

Figure 9. Controlled-environment X-ray diffraction patterns of a kaolinite-hydrazine intercalate in the 7 to 11 ° 20 region, obtained as a function of pressure at 298 K.

Johnston, C.T. Stone, D.A. Applewhite, L.A. Vibrational spectroscopic study of tire kaolinite-hydrazine intercalation complex. The Third Conference on the Environmental Chemistry of Hydrazine Fuels, Panama City, FL 15-17 Sept. 1987 1987, ESL-TR-87-74,118. 

C.T. Johnston, D.L. Bish, J. Eckert L.A. Brown (2000). J. Phys. Chem. B, 104, 8080-8088. Infrared and inelastic neutron scattering study of the 1.03-and 0.95-nm kaolinite-hydrazine intercalation complexes. 

Ghorayeb AM, Friend RH (1987) Transport and optical propoties of the hydrazine intercalation complexes of TiS2, TiSc2 and ZrS2. J Phys C 20 4181-4200... 

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