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** Hybrid orbitals non-orthogonal **

B. Fdrster-Coulson-Moffitt Orbitals and Non-orthogonal Valence Bond Hybrid Orbitals [Pg.55]

TABLE 2. Hybridization and overlap values obtained with non-orthogonal hybrid orbitals within a valence bond calculation of cyclopropane" [Pg.57]

TABLE 1. Hybridization and interorbital angles in cyclopropane using orthogonal hybrid orbitals [Pg.57]

It is usually of interest to express the atomic orbitals as functions of the hybrid orbitals. As the transformation matrix is orthogonal, its inverse is [Pg.110]

All three orbitals are in the same plane, and each one is 120° from each of the other orbitals. The remaining p orbital is orthogonal to (perpendicular to the plane of) the three hybridized orbitals. [Pg.79]

As can be seen from Table 2, the amount of s-character of the CH hybrid orbital of 1 is indeed increased relative to that of the CH hybrid orbitals of ethene, ethane and methane while at the same time the s-character of the CC hybrid orbitals is decreased. This seems to confirm predictions based on model calculations with orthogonal hybrid orbitals. However, closer inspection of the data in Table 2 reveals that s-character of the CH hybrid [Pg.57]

See also in sourсe #XX -- [ Pg.57 , Pg.58 ]

** Hybrid orbitals non-orthogonal **

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