Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

How to Structure a Degenerate Space

Theorem 1 If a matrix commutes with all the matrices of an irreducible representation, the matrix must be a multiple of the unit matrix  [Pg.107]

In octahedral transition-metal complexes, the i-orbitals, which transform as the E irrep, are and d 2 y2. They are seen to match E9) and Ee), respectively. The [Pg.107]

This operator connects the two components, and, therefore, if we require that the matrix be of the specified form, then the relative phase freedom is lifted. With such a connecting element, one can indeed easily construct a proper ladder operator  [Pg.108]

In Appendix D we list standard conventions that are frequently used to define canonical basis sets for degenerate irreps. [Pg.108]

For the octahedral T state, the standard basis complies with the transformation [Pg.108]


See other pages where How to Structure a Degenerate Space is mentioned: [Pg.103]    [Pg.107]    [Pg.107]   


SEARCH



A-space

Degenerate structures

© 2024 chempedia.info