Horizontal touch cyclic voltammetry pressure

Calculated as the percentage of the voltammogram peak area relative to that measured in the absence of the calix[6]arene monolayer. Guest induced increase ( f) or decrease (-) are shown in the parentheses. Measured by horizontal touch cyclic voltammetry with an HOPG electrode at an applied surface pressure of 10 mN m . The marker was added as [Co(l,l(>-phenanthroline)3](C104)2 (1.00 x 10 M). 

Figure 17. Experimental system for the measurement of surface pressure-molecular area (n-A) isotherms and the horizontal touch cyclic voltammetry/ and schematic representations for the control of permeabilities through oriented monolayers formed at low and high applied surface pressures.

Horizontal Touch Cyclic Voltammetry with a Condensed Monolayer of a Cyclodextrin Derivative. To obtain experimental evidence supporting that such a mode of permeability control is possible, an approach based on horizontal touch cyclic voltammetry was carried out for a condensed monolayer of 4, which was formed at the air/water interface in a Langmuir trough 14), This technique, first used by Fujihira (25) and recently sophisticated by Bard (2d, 27), enables the investigation of the electrochemical properties of oriented monolayers at varying packing densities under an appropriately controlled surface pressure. 

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