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Homonuclear diatomic molecules of later rows

For Br2, the 4p orbitals would form a similar set, but the numbering would go even higher as we would have to allow for Is, 2s, 2p, 3s, 3p, 4s and 3d orbitals. The s and p orbitals will combine as in Cl2, the 3d orbitals form two a orbitals, four n orbitals and four orbitals of a new type, 6 (delta, the Greek equivalent of d).  [Pg.58]

Although elemental sulfur is a solid under normal conditions of temperature and pressure, S2 molecules can be observed in sulfur vapour when the solid is heated. Draw an orbital energy-level diagram for S2, showing the orbitals made from the 3p on S. Predict the bond order of S2 and state whether or not it will be paramagnetic. [Pg.60]


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