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Hirschfelder-Silbey theory

Perturbation equations of the Hirschfelder-Silbey theory can be derived by using the concept of the primitive (localized) wave function F formally defined as,... [Pg.23]

Equation (1-54) holds for any choice of the coefficients cM, so an extra condition needed to uniquely specify F must be imposed. The function F of the Hirschfelder-Silbey theory fullfils the following condition ... [Pg.23]

ATM = Axilrod-Teller-Muto term CCD = coupled-clu.s-ter doubles CCSD = coupled-cluster singles and doubles CP = counterpoise (technique) DCBS = dimer-centered basis set HS = Hirschfelder-Silbey theory SAPT = symmetry-adapted perturbation theory SRS = symmetrized Rayleigh-Schrd-dinger series. [Pg.1376]

Polymeropoulos EE, Adams WH (1978) Exchange perturbation theory, III. Hirschfelder-Silbey type. Phys Rev A 17 24-29... [Pg.135]

All the SAPT methods considered so far have used a single operator projecting onto a specific subspace c a b- The HS perturbation theory, introduced by Hirschfelder and Silbey [50], follows a different, multistate philosophy. It performs a perturbation expansion for a primitive func-... [Pg.61]

See other pages where Hirschfelder-Silbey theory is mentioned: [Pg.22]    [Pg.175]    [Pg.47]    [Pg.22]    [Pg.175]    [Pg.47]    [Pg.22]    [Pg.171]    [Pg.172]    [Pg.1385]   
See also in sourсe #XX -- [ Pg.2 , Pg.1385 ]



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