Hindered rotor Hamiltonian

Because hindered rotors involve densely spaced energy levels, it is possible to treat the problem classically. This has been done for the case of a two-dimensional hindered rotor (Jordan et al., 1991) which is particularly important in the dissociation of loose transition states, a topic to be discussed in the following chapter. The classical phase space integral is solved using the Hamiltonian ... 

---