High-spin organic molecules magnetism-design

Intra- and inter-molecular spin alignment the conceptual framework of organic molecular magnets 182 Design of high-spin organic molecules 185 Exchange interaction 186... 

Organic building blocks for magnetism - design of high-spin organic molecules 109... 

Figure 14.32 C shows the NBMOs of m-xylylene, another prototype high-spin system. This structure also has two more than non- atoms. As such, its NBMO are non-disjoint, and a triplet state for the biradical is preferred. In our discussion of organic magnetic materials in Section 17.3 we will see that this /non- approach to predicting spin states can be extended to a remarkable degree, allowing the rational design of very high-spin organic molecules.

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