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High-spin electron configurations

Low-spin (L) and high-spin (H) electron configurations of the d orbitals of a metal centre A is the crystal field splitting... [Pg.146]

In the structure, the copper (or chromium) atom has a greatly distorted octahedral coordination, with two bond distances much longer than the other four (difference = 0.38 A for Cu, 0.36 A for Cr) and small, but significant differences between the pairs of short distances. The major distortion is correlated with the d9, or high-spin d4, electronic configuration of Cu(II) and Cr(II), respectively, giving an uneven occupation of the eg orbitals—the Jahn-Teller effect. The differ-... [Pg.86]

See other pages where High-spin electron configurations is mentioned: [Pg.1102]    [Pg.150]    [Pg.98]    [Pg.443]    [Pg.549]    [Pg.48]    [Pg.61]    [Pg.169]    [Pg.631]    [Pg.118]    [Pg.601]    [Pg.439]    [Pg.110]    [Pg.122]    [Pg.138]    [Pg.243]    [Pg.287]    [Pg.288]    [Pg.163]    [Pg.94]    [Pg.117]    [Pg.264]    [Pg.753]    [Pg.55]    [Pg.56]    [Pg.57]    [Pg.325]    [Pg.351]    [Pg.352]    [Pg.133]    [Pg.212]    [Pg.888]    [Pg.3]    [Pg.146]    [Pg.932]    [Pg.900]    [Pg.10]    [Pg.13]    [Pg.106]    [Pg.603]    [Pg.247]    [Pg.254]    [Pg.290]    [Pg.32]    [Pg.34]    [Pg.42]    [Pg.56]    [Pg.380]   


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High-spin configurations

Spin configurations

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