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High-nuclearity carbonyl clusters reduction reactions

Redox condensation can occur by the simple addition of a mononudear carbonyl cationic spedes to an anionic cluster as shown in equation (3.18). Such condensation reactions allow for a stepwise and controlled construction of higher nuclearity clusters whereby the regeneration of a suffidently high negative charge on the cluster can be accomplished by appropriate reduction or deprotonation steps in the condensation sequence. [168]... [Pg.120]


See other pages where High-nuclearity carbonyl clusters reduction reactions is mentioned: [Pg.108]    [Pg.761]    [Pg.148]    [Pg.222]    [Pg.218]    [Pg.295]    [Pg.4016]    [Pg.4015]    [Pg.76]    [Pg.424]    [Pg.295]    [Pg.913]    [Pg.152]    [Pg.1859]    [Pg.1858]   
See also in sourсe #XX -- [ Pg.174 , Pg.175 , Pg.176 , Pg.177 ]




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Carbonyl clusters

Carbonyl reduction

Cluster high-nuclearity

Cluster nuclearity

Clustering reaction

High clustering

High reactions

High-nuclearity carbonyl clusters

High-nuclearity carbonyl clusters reactions

Nuclear reactions

Reduction carbonylation

Reductive reactions carbonylation

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