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Hexafluoroace tylacetone

Fig. 4.21 Distribution constants, Ky)c, for uncharged metal complexes MA vs. distribution constants for the corresponding undissociated acid ligand HA solid circles Zn(II), solid triangles Co(III). Variation with ligand composition HFA hexafluoroace-tylacetone, TFA trifluoroacetylacetone, AA acetylacetone, FTA 2-furoyltrifluoroacetone, TTA 2-thenoyltrifluoroacetone, PTA pivaloyltrifluoroacetone, BFA benzoyltrifluoroace-tone, BZA benzoylacetone. (From Ref. 36.)... [Pg.179]

Gatteschi et al. [44] prepared linear chain polymers that were composed of M(hfac)2(NIT)R, where M is Cu(II), Ni(II), or Mn(II) (NIT)R is 2-alkyl-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide and hfac is hexafluoroace-tylacetonate. Ferromagnetic ordering was observed for those polymers composed of Mn(hfac)2(NIT)Et (36) and Ni(hfac)2(NIT) Pr, respectively. The critical temperature for each polymer was 8.6 and 5.3 K, respectively. [Pg.167]




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