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Heteronuclear correlation spectroscopy reactions

The hydroformylation of an unsaturated steroid proceeded in high chemo-, diastereo-, and regioselectivity (Scheme 14.9) with diastereoselectivity assigned by correlation spectroscopy (COSY), and heteronuclear correlation spectroscopy (HETCOR) spectra." This reaction of this trisubstituted alkene used a [Rh(nbd)Cl]2 precursor (nbd) and P( -Bu)3 as a ligand, at 120°C and pressures of 100-120 bar. [Pg.402]

Nuclear Overhauser effect (NOE) difference measurements were used to assign structure 79 for the product of reaction of diphenylnitrile imine with 5-ethylsulfonyl-2-methyl(27/)pyridazinone. Thus in the H NMR spectrum the ot/, o-protons of the arylhydrazino moiety (which were identified by two-dimensional heteronuclear multiple quantum correlation (2-D HMQC) spectroscopy) were shown in differential NOE (DNOE) experiment to be significantly enhanced on irradiation of pyridazine hydrogen H-7, proving their steric proximity <2000JST13>. [Pg.607]

See other pages where Heteronuclear correlation spectroscopy reactions is mentioned: [Pg.559]    [Pg.10]    [Pg.248]    [Pg.309]    [Pg.87]    [Pg.109]    [Pg.258]    [Pg.264]    [Pg.270]    [Pg.13]    [Pg.130]    [Pg.322]    [Pg.456]    [Pg.324]    [Pg.690]    [Pg.310]    [Pg.358]    [Pg.241]    [Pg.363]    [Pg.115]   
See also in sourсe #XX -- [ Pg.236 ]



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Correlated spectroscopy

Correlation spectroscopy

Heteronuclear correlation spectroscopy

Heteronuclear correlations

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