Heteromolecular associate ionization

In some cases, rearrangement of bonds leads to formation of electro-neutral ionic associate in binary solvents where heteromolecular associates are formed  

In many cases, ionic associate undergoes the process of ionic dissociation (see paragraph 9.2.5). If permittivity of mixture is not high, interaction can limit itself to formation of non-ionogenie ionie associate, as exemplified by the binary solvent anisol-m-cresol, where the following equilibrium is established  

CeHpCHj + CHfi,HfiH C HfiCH CHf.HflH [C HflCH Hf CHfiJHJD 

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General analysis of the binary solvent mixtures formed by two solvate active components (these solvents are often used in analytical and electrochemistry) was conducted to evaluate their effect on H-acids. The analysis was based on an equation which relates the constant of ion association, K, of the solvent mixture and constants of ion association of the acid Kj and K of each component of the mixed solvent, using equilibrium constants of scheme [9.105] - heteromolecular association constant, ionization constant of the... 

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