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Heteroleptic lithium magnesiates

Only one example [Li2Mg (NDipp)2SiMe2)2] 15 (Fig. 10) of a hi er-order heteroleptic amido magnesiate has been published between 2007 and 2015. It incorporates the bulky dianionic bis(amido)silane ligand [Me2Si (DippN)2j (where Dipp is diisopropylphenyl). The Mg atom is tetrahedrally disposed—r (N,N)-bound to two bis(amido)silane ligands—and the lithium atoms lithium atoms is provided by rr-coordination to an arene-C atom (Fig. 10). [Pg.7]

Garcia-AlvarezJ, Graham DV, Hevia E, Kennedy AR, Mulvey RE. Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetyhdes structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates. Dalton Trans. 2008 (11) 1481—1486. [Pg.45]

See other pages where Heteroleptic lithium magnesiates is mentioned: [Pg.9]    [Pg.9]    [Pg.9]    [Pg.9]    [Pg.118]    [Pg.122]    [Pg.127]    [Pg.18]    [Pg.107]   
See also in sourсe #XX -- [ Pg.9 , Pg.13 ]



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