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Heteroboranes isomerisation

Towards Experimental Mapping of the Mechanism of Heteroborane Isomerisation... [Pg.329]

It is only partially satisfying to disprove one mechanism and clearly better to be able to say something positive about another. This we have done via the isolation, for the first time, of an intermediate in the isomerisation of one icosahedral heteroborane into another. [Pg.332]

Thus, overall, we find good correspondence between the theoretical predictions of Wales and our experimental results. Together these point towards the mechanism of isomerisation of icosahedral heteroboranes being via a series of sequential dsd steps, route b+e producing an isolatable intermediate and route f+k+i then producing the... [Pg.334]

See other pages where Heteroboranes isomerisation is mentioned: [Pg.329]    [Pg.330]    [Pg.329]    [Pg.330]    [Pg.329]    [Pg.330]    [Pg.329]    [Pg.330]    [Pg.329]    [Pg.332]    [Pg.329]    [Pg.332]   
See also in sourсe #XX -- [ Pg.329 ]

See also in sourсe #XX -- [ Pg.329 ]



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Isomerisations

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