Heterobimetallic Complexes of the Group 11 Metals

Mathur, and coworkers [167] report the photoreaction of a silver(I) his(trifluoromethyl) aurate(I) salt that leads to an unsupported gold(II) trifluoromethyl  

Extensive reviews of gold-heterometal interactions [169], and of complexes of d copper, silver, and gold with other metals, cover developments through 2011 [170]. A selection of recent advances appears here. 

Puddephatt, R.J. (1978) The Chemistry of Gold, Elsevier Scientific Publishing Company, Amsterdam. 

(1990) Atoms in Molecules A Quantum Theory, Oxford University Press, Oxford. 

Gambarotta, S., Floriani, C., Chiesi-Villa, A., and Guastini, C. (1985) / Chem. Soc., Chem. Commun., 1087. 

---

Heterobimetallic Complexes of the Group 11 Metals 1421 Figure 11.31 An unsupported gold(ll) trifluoromethyl complex. 

---