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Heteroatomic Chalcogen Cations

Several approaches have been used for the synthesis of heteroatomic chalcogen cations, including (a) direct oxidation of a mixture of two chalcogens with oleum, MF5 (M = As, Sb) or transition metal halides, (b) reaction of a chalcogen with a homoatomic cation of another chalcogen and (c) compro-portionation of the homoatomic cations of two different chalcogens. [Pg.293]


Similar, but less stable, selenium homocycles, as well as mixed sulfur-selenium related heterocycles formed by heteroatom replacement, are also well docnmented. Cationic chalcogen homocycles are also known and have been reviewed. ... [Pg.5998]


See other pages where Heteroatomic Chalcogen Cations is mentioned: [Pg.293]    [Pg.294]    [Pg.293]    [Pg.294]    [Pg.410]    [Pg.293]    [Pg.27]    [Pg.368]    [Pg.95]    [Pg.96]    [Pg.175]    [Pg.72]    [Pg.39]   


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