Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Hermitian operators nondegenerate

The solutions for the unperturbed Hamilton operator from a complete set (since Ho is hermitian) which can be chosen to be orthonormal, and A is a (variable) parameter determining the strength of the perturbation. At present we will only consider cases where the perturbation is time-independent, and the reference wave function is nondegenerate. To keep the notation simple, we will furthermore only consider the lowest energy state. The perturbed Schrodinger equation is... [Pg.69]

We first require Theorem 1. Let X be an operator defined in a finite space. X is Hermitian iff (1) its eigenvalues are real, and (2) its nondegenerate eigenvectors are mutually orthogonal. It is well known [151] that if X is Hermitian then (1) and (2) follow, and that neither (1) nor (2) is a sufficient condition for the Hermiticity of X. However, properties (1) and (2) together imply that X is Hermitian [152]. [Pg.523]


See other pages where Hermitian operators nondegenerate is mentioned: [Pg.252]    [Pg.403]    [Pg.24]    [Pg.252]    [Pg.252]    [Pg.173]    [Pg.174]    [Pg.188]    [Pg.488]    [Pg.523]   
See also in sourсe #XX -- [ Pg.173 ]




SEARCH



Hermitian

Nondegenerate

© 2024 chempedia.info