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Hentriacontane-14,16-dione synthesis

The reaction mechanisms advanced are discussed in the light of a new hypothesis and in relationship to feeding experiment data, chemical genetic evidence and an abiological biomimetic synthesis of B-diketones. As hentriacontan-14,16-dione 6 is the commonest B-diketone found in cereal plant waxes we shall use it as model for our discussion (Scheme). [Pg.553]

Furthermore, route via C acylation presents a clear chemical homology with a published biogenetic-type synthesis of hentriacontane-14,16--dione accomplished from appropriate derivatives of B-ketostearate and myristic acid. ... [Pg.554]


See other pages where Hentriacontane-14,16-dione synthesis is mentioned: [Pg.643]    [Pg.643]    [Pg.643]    [Pg.643]    [Pg.643]    [Pg.643]    [Pg.643]    [Pg.645]    [Pg.490]   
See also in sourсe #XX -- [ Pg.645 ]

See also in sourсe #XX -- [ Pg.8 , Pg.645 ]

See also in sourсe #XX -- [ Pg.8 , Pg.645 ]




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