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Hapto number

Hapto number Formal charge Electrons donated... [Pg.1314]

For the elimination to proceed, a vacant coordination site at the metal centre is required. In the example quoted the square planar platinum complex has only a 16-electron configuration, so it is coordinatively unsaturated. In 18-electron compounds this site has to be provided by dissociation or by change of hapto number of a ligand. [Pg.217]

Electrons from the ligands this depends, naturally on the ligands. For hydrocarbon ligands, the number is equal to the hapto number. Single-bonded ligands (hydride, halide etc) count as 1 (although a bridging halide counts as 2 - a lone-pair donor), while carbenes and carbynes count as 2 and 3, respectively. Lone-pair donors, such as phosphines and CO, count as 2. [Pg.11]


See other pages where Hapto number is mentioned: [Pg.187]    [Pg.187]    [Pg.1312]    [Pg.1314]    [Pg.1314]    [Pg.187]    [Pg.334]    [Pg.1312]    [Pg.1314]    [Pg.187]    [Pg.1070]    [Pg.300]    [Pg.437]    [Pg.191]    [Pg.323]    [Pg.157]    [Pg.229]    [Pg.455]    [Pg.3]    [Pg.11]    [Pg.12]    [Pg.441]   
See also in sourсe #XX -- [ Pg.187 ]

See also in sourсe #XX -- [ Pg.187 ]

See also in sourсe #XX -- [ Pg.300 ]

See also in sourсe #XX -- [ Pg.191 ]

See also in sourсe #XX -- [ Pg.3 ]




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