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Handedness geometrical chirality

The condition of handedness or lack of superimposabil-ity of molecules differing only with respect to the stereochemical arrangement of identical substituents around a tetrahedral center. In 1893, Lord Kelvin succinctly defined chirality I call any geometrical figure, or any group of points, chiral, and say that it has chirality, if its image in a plane mirror, ideally realized, cannot be brought to coincide with itself. ... [Pg.144]

In its geometrically most regular form, shown in Figure 21, the (10,3)-a net has cubic symmetry and angles at nodes are all 120°. 4-Fold helices run parallel to the axes. All the helices have the same handedness, making the net as a whole chiral. Wells foresaw, before real examples were known, that the (10,3)-a net is in principle capable of participating in interpenetration not only with an identical net... [Pg.92]


See other pages where Handedness geometrical chirality is mentioned: [Pg.348]    [Pg.192]    [Pg.50]    [Pg.73]    [Pg.12]    [Pg.136]    [Pg.207]    [Pg.9]    [Pg.995]    [Pg.1030]    [Pg.976]    [Pg.431]    [Pg.538]    [Pg.9]    [Pg.1571]    [Pg.8]   
See also in sourсe #XX -- [ Pg.2 ]




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Geometrical chirality

Handedness

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