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Halous acids and halites

In the case of fluorine, the only oxyacid known is HOF. For acids having the formula HX02 (or more accurately, HOXO), only HC102 is well characterized and even for that acid only aqueous solutions are known. Consequently, the discussion will be limited to chlorous acid and its salts. [Pg.395]

Sodium chlorite can be prepared by the reaction of C102 with aqueous NaOH  [Pg.395]

The chlorite ion is angular (C2v) with a bond angle of about 111°. A solution of HC102 can be prepared by acidifying a chlorite solution with H2S04. In accord with b = 1 in the general formula (HO)aXO, the acids are weak (see Chapter 5). [Pg.395]

It remains now to consider the equilibria of the oxo anions not yet mentioned and their kinetic relations to those we have discussed. Halite ions and halous acids do not arise in the hydrolysis of the halogens. HI02 apparently does not exist, HBr02 is doubtful, while HC102 is not formed by disproportionation of ClOH if for no other reason than that the equilibrium constant is quite unfavorable ... [Pg.477]

See other pages where Halous acids and halites is mentioned: [Pg.561]    [Pg.395]    [Pg.567]    [Pg.134]    [Pg.561]    [Pg.395]    [Pg.567]    [Pg.134]    [Pg.859]    [Pg.859]    [Pg.268]    [Pg.544]   
See also in sourсe #XX -- [ Pg.543 , Pg.544 ]



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