Halomethanes bond lengths

Halomethane Bond length (pm) (kJ/mol) (kcal/mol) Dipole moment (D)... [Pg.358]

Table 7.1 Bond lengths r and bond strengths B of various halomethanes [3, 4]...

Table I. Carbon-Fluorine Bond Lengths and Bond Dissociation Energies in Halomethanes (42-43)...

The magnitude of a dipole moment depends on the size of the partial charges, the distance between them, and the polarizability of the three pairs of imshared electrons on each halogen. For the halomethanes, the dipole moment increases as the electronegativity of the halogen and the bond length increase. These two trends run... [Pg.339]

Halomethane Electronegativity of Halogen Caitran-Halogen Bond Length (pm) Dipole Moment (debyes, D)... [Pg.340]

The C-X bond-dissociation energies in the halomethanes, CH3X, decrease along the series F, Cl, Br, I. At the same time, the C-X bond lengths increase (Table 6-1). The bond between carbon and halogen is made up mainly by the overlapping of an sp hybrid orbital on carbon... [Pg.211]

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