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Halogen complexes three-coordinate

X-ray structural investigations of these complexes show the tellurium to be three-coordinated with bonds to a carbon, a halogen, and a chalcogen atom2,4. [Pg.248]

In method (ii), the group X (e.g., a halogen) may function as a three-electron donor when present as a bridging group, but as a one-electron donor when combined to one metal center. The simple act of bridgeopening creates a vacant coordination site on one metal atom. Behavior of this sort is invoked to explain the stereospecific incorporation of I3CO in the complex Os3(CO)10Cl2. [Pg.261]

See other pages where Halogen complexes three-coordinate is mentioned: [Pg.125]    [Pg.22]    [Pg.313]    [Pg.1342]    [Pg.685]    [Pg.310]    [Pg.327]    [Pg.790]    [Pg.536]    [Pg.539]    [Pg.2810]    [Pg.383]    [Pg.2]    [Pg.37]    [Pg.535]    [Pg.538]    [Pg.2809]    [Pg.1331]    [Pg.2152]    [Pg.3181]    [Pg.25]    [Pg.310]    [Pg.313]    [Pg.912]    [Pg.366]    [Pg.472]    [Pg.373]    [Pg.215]    [Pg.116]    [Pg.49]    [Pg.41]    [Pg.53]    [Pg.727]    [Pg.996]    [Pg.479]    [Pg.90]    [Pg.313]    [Pg.3]    [Pg.113]    [Pg.207]    [Pg.343]    [Pg.28]    [Pg.205]    [Pg.5]    [Pg.65]    [Pg.34]    [Pg.133]    [Pg.86]   
See also in sourсe #XX -- [ Pg.2 , Pg.684 ]



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Halogen complexes Halogens

Three coordination

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