Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Halides reduction using 3SiH

Radical reductions with [(CH ) Si]3SiH.1 In combination with an initiator, this silane (I) reduces not only alkyl halides, but also thionoesters (used for deoxygenation of secondary alcohols) and selenides. However, cleavage of C-S bonds is inefli-... [Pg.374]

Me3Si)3SiH is a less stable oil and is oxidized under aerobic conditions, while 1,1,2,2-tetraphenyldisilane (TPDS) (Q) is stable crystal under aerobic conditions, and remains stable even when left on a table for 6 months. TPDS can be used for the reduction of organic halides, chalcogenides, and xanthates, and can be used for C-C bond formations... [Pg.250]

See other pages where Halides reduction using 3SiH is mentioned: [Pg.111]    [Pg.74]    [Pg.171]    [Pg.439]    [Pg.91]    [Pg.131]    [Pg.42]    [Pg.249]    [Pg.45]    [Pg.152]    [Pg.749]   
See also in sourсe #XX -- [ Pg.47 ]



SEARCH



Halides reduction

© 2024 chempedia.info