H. Taube

A. D. Allen and C. V. Senoff, Chem. Commun., 1965, 621-2. The unprecedented nature of the reaction can be gauged from the fact that this paper was rejected for publication by J. Am. Chem. Soc. on the grounds that it was impossible, before being accepted by Chem. Commun., See also H. Taube, The researches of A. D. Allen — an appreciation. Coord. Chem. Rev. 26, 1-5 (1978). 

Inner-sphere. Here, the two reactants first form a bridged complex (precursor)- intramolecular electron transfer then yields the successor which in turn dissociates to give the products. The first demonstration of this was provided by H. Taube. He examined the oxidation of ICrfHoOijj by lCoCl(NHr)< and postulated that it occurs as follows ... 

H. Taube (Stanford) mechanisms of electron transfer reactions of metal complexes. 

Mechanisms of redox reactions in simple chemistry. H. Taube, Adv. Inorg. Chem. Radiochem.,... 

Substitution reactions of ruthenium ammines. H. Taube, Comments Inorg. Chem., 1981, 1, 17-31... 

Redox reactions between metal complexes. H. Taube, Angew. Chem., Int. Ed. Engl., 1984, 23, 329-339 (100). 

Mixed valence molecules electronic delocalisation and stabilisation. D. E. Richardson and H, Taube, Coord. Chem. Rev., 1984, 60,107 (40). 

Mechanisms of Redox Reactions of Simple Chemistry H. Taube... 

Professor H. Taube Department of Chemistry Stanford University Stanford, California 94305... 

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