Guntelberg charging process

In the Guntelberg charging process, the central ion i is assumed to be in a hypothetical condition of zero charge. The rest of the ions, fully charged, are in the positions that they would hypothetic ly have were the central ion charged to its normal value z,.Co i.e.,theotherionsconstituteanionicatmosphereenvelopingthecentralion (Fig. 3.40). The ionic cloud sets up a potential yfama ... 

Since during the charging only ions of the th type are considered, the Guntelberg charging process gives that part of the chemical potential due to electrostatic interactions. 

Now, the Guntelberg charging process was suggested several years after Debye and Htickel made their theoretical calculation of the activity coefficient. These authors... 

Grove, and power from chemical reactions, diagianmiated, 12 Grove, the discovery of fuel cells, 2 Guntelberg charging process, 302 Gurney... 

Describe the difference between the Guntelberg and Debye charging processes. Which process should be more effective in deriving an equation for the activity coefficient ... 

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