Group VII and Hydride Donors

Endres, H. J. Keller, M. Megnamisi-Belombe, W. Morini, and D. Nothe, Inorg. Nuclear Chem. Letters, 1974,10, 467. 

In contrast, addition of ethanolic solutions of thioamides to aqueous PdCl2 yields monomeric square-planar complexes of type [PdCljjSCR NHR2) ] (R1 = Me, Ph, 

A tetrachloroaluminate has been isolated for the first time by reaction of PdCl2 with excess A1C13 at 200 °C.24 An X-ray powder pattern was run and the low magnetic moment indicates a square-planar PdCl4 co-ordination. 

Linarte-Lazcano, M. Paez-Pedrosa, J. Sabadie, and J. E. Germain, Bull. Soc. chim. France, 1974, 1129. 

The heats of the displacement reactions of chloropalladium complexes (equation 8) 

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Platinum (n)—Group VII and Hydride Donors. SCF—Xa calculations have been made for the ions [MC14]2 (M = Pd or Pt) (see p. 384).13 In addition the extended Hiickel MO method has been employed to calculate activation energies of the halide-... 

Osmium(n).—Group VII Donors. Hydrido- and halogeno-carbonyl complexes. Carbonylation of [OsHX(CO)(PCy3)2] has produced the novel dicarbonyl hydride [OsHX(CO)2(PCy3)2] (X = Cl or Br Cy = tricyclohexyl).17 I.r. and n.m.r. data indicate the geometry (17). Addition of other ligands to the five-co-ordinate... 

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