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Group transfer reactions solved problems

Electrocyclic, sigmatropic, and cycloaddition reactions are subsequently described in Chapters 2, 3, and 4, respectively. Chapter 5 is devoted to a study of cheletropic and 1,3-dipolar cycloaddition reactions as examples of concerted reactions. Many group transfer reactions and elimination reactions, including pyrolytic reactions, are included in Chapter 6. There are solved problems in each chapter that are designed for students to develop proficiency that can be acquired only by practice. These problems, about 450, provide sufficient breadth to be adequately comprehensive. Solutions to all these problems are provided in each chapter. Finally, in Chapter 7, we have compiled unworked problems whose... [Pg.374]

The same experimental procedure can be used with alkylidenemalonate and other related Michael-acceptors, as well as nitroolefins.26 However, under these reaction conditions only one of the two R groups of R2Zn is transferred to the enone. This problem can be solved by using mixed diorganozincs of the... [Pg.160]

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