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Group-transfer reactions radical composites

Whereas additions of carbon radicals to alkene moieties are the best characterized homolytic additions, carbon radicals are known to add to a wide range of unsaturated systems. These include polyenes, alkynes, arenes, heteroarenes, carbon monoxide,isonitriles, °° ° nitriles, ° imines and derivatives, ° ° aldehydes,nitrones, and thiones. ° Many of these reactions, such as addition of an alkyl radical to a carbonyl group, ° are thermodynamically unfavorable and readily reversible, and they form the basis of composite group-transfer reactions discussed below. [Pg.150]

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See also in sourсe #XX -- [ Pg.155 ]



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Group transfer reactions radicals

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