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Group-transfer imidoylation

Radical-mediated group-transfer imidoylation with isonitriles... [Pg.274]

Intensive investigations have been directed recently to group-transfer imidoylation of organotellurium compounds with isonitriles. " ... [Pg.274]

Because sp carbon-tellurium bonds are often unstable under photoirradiation conditions, carbotelluration producing sp -carbon-tellurium bonds occurs preferentially. Successful telluro group transfer cyclization has also been reported [119g]. Carbonyl tellurides are useful precursors for carbonyl radicals, which are employed for cyclization and addition reactions [127]. The reaction of diorganyl tellurides wifh isocyanides leads to fhe formation of imidoyl tellurides in high yields [128]. The carbotelluration system has also recenfly been applied to living radical polymerization (Scheme 15.52) [129]. [Pg.835]

See other pages where Group-transfer imidoylation is mentioned: [Pg.76]    [Pg.76]    [Pg.69]    [Pg.643]    [Pg.665]    [Pg.291]    [Pg.287]    [Pg.378]    [Pg.21]    [Pg.548]    [Pg.167]    [Pg.66]   
See also in sourсe #XX -- [ Pg.274 ]



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