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Group phosphanide cluster

The Ca/Sn-mixed metalated phosphanide-phosphandiide cluster 43 crystallizes in the triclinic space group PI (71). It consists of a trigonal Ca2SnP2 bipyramid, where the phosphandiide P centers serve as ju -bridging centers to the metals. The two phosphanide ligands, however, are. -bridging between two Ca and Ca/Sn centers (Fig. 32). Both Ca ions are octahedrally coordinated. [Pg.280]

Scheme 3.6-14. Structural variety in group 2 metal and tin(+2) phosphanide (arsanide)-phosphandiide (arsandiide) cluster chemistry. Scheme 3.6-14. Structural variety in group 2 metal and tin(+2) phosphanide (arsanide)-phosphandiide (arsandiide) cluster chemistry.
See other pages where Group phosphanide cluster is mentioned: [Pg.236]    [Pg.237]    [Pg.391]    [Pg.392]    [Pg.404]    [Pg.404]    [Pg.408]    [Pg.236]    [Pg.237]    [Pg.5]   
See also in sourсe #XX -- [ Pg.404 ]



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