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Group oxofluorides

Table 1. Physical and Thermodynamic Properties of Helium-Group Gas Fluorides, Oxofluorides, and Oxides... Table 1. Physical and Thermodynamic Properties of Helium-Group Gas Fluorides, Oxofluorides, and Oxides...
The oxofluoride ONF3 is also known. Like it is isoelectronic with an(j must be described by a similar valence structure (3). N2F4 is interesting in that like N204 it readily dissociates into NF2 radicals. Double-bonded N2F2 exists in cis (4) and trans (5) forms, the former being thermodynamically more stable. The point groups are C2v (4) and C2h (5). [Pg.204]

The major problems associated with heptacoordinadon in main-group fluorides and oxofluorides have been resolved. A detailed discussion of... [Pg.66]

Inorganic main-group fluorides or oxofluorides offer a unique opportunity to study unusually high coordination numbers and problems associated widi them, such as the steric activity of free valence electron pairs, steric crowding of the ligands, and fluxionality. Of particular interest are heptacoordinated species which could exist either... [Pg.66]

See other pages where Group oxofluorides is mentioned: [Pg.23]    [Pg.1273]    [Pg.181]    [Pg.201]    [Pg.548]    [Pg.524]    [Pg.571]    [Pg.1273]    [Pg.667]    [Pg.770]    [Pg.341]    [Pg.4]    [Pg.66]    [Pg.67]    [Pg.69]    [Pg.71]    [Pg.73]    [Pg.75]    [Pg.81]    [Pg.83]    [Pg.85]    [Pg.87]    [Pg.87]    [Pg.89]   
See also in sourсe #XX -- [ Pg.499 ]

See also in sourсe #XX -- [ Pg.552 , Pg.569 ]

See also in sourсe #XX -- [ Pg.631 , Pg.633 ]



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Oxofluorides

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