Group-IVB bonds

Compounds Li[R3EE R3], with group-IIIB-group-IVB bonds are accessible from ER3 (E = Al, Ga, In, Tl R = Me, Ph) combined with LiE R3 (E = Si, Ge, Sn) polysubstituted forms, e.g., Li[MenTl(SnMe3)4 n] (n = 0-3), can also be obtained . Side reactions yield Sn2Meg, ascribed to disproportionation ... [Pg.42]

In reactions of silanes with complexes containing metal-group-IVB bonds metal-bonds are formed by exchange ... [Pg.294]

Of the various possibilities for the group IB-group IVB bond, only the synthesis of compounds containing a cr or bond between the group-IB metal and the one-electron (e.g., Me, Ph, C=CR) or two-electron (e.g., CO, olefin) carbon ligands is known in detail. The synthesis of -metal IB-carbon-containing compounds is discussed in 5.6.2.3.6. [Pg.293]

Organolead bonds are the most reactive of the organo-group-IVB bonds, but reactions with HgXj have little synthetic value °. [Pg.350]

Reaction with Group IIIB-Group IVB bonds ... [Pg.76]

Reaction with Fe(CO)s 4, 2.9.15.1.1 Reaction with Group IIIB-Group IVB bonds 4, 2.6.11.1... [Pg.841]

The results of a systematic study of the cleavage of transition-metal-Group IVb bonds by halogens have been reported during the present period and kinetic data for the following reactions are given " ... [Pg.322]

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