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Group 12 halides reaction with, phosgene

Reactions of phosgene with Group 1 and Group 2 halides... [Pg.341]

Reactions of phosgene with Group 13 halides 9.1.2.1 Reaction of phosgene with boron(in) fluoride... [Pg.342]

In the alkyl chain hydroxy groups or side chains may be present. The reaction is somewhat different when acyl halides are used. Hydroxymethanediphosphonic acid is prepared by reacting phosgene with an alkali metal, dialkyl phosphite. The reaction is rapid and exothermic. The temperature is controlled between 10 and 20°C. After hydrolysis with HC1, hydroxymethanediphosphonic acid is recovered [91,92]. [Pg.571]

A carboxylic acid (not the salt) can be the nucleophile if F is present. Mesylates are readily displaced, for example, by benzoic acid/CsF. Dihalides have been converted to diesters by this method. A COOH group can be conveniently protected by reaction of its ion with a phenacyl bromide (ArCOCH2Br). The resulting ester is easily cleaved when desired with zinc and acetic acid. Dialkyl carbonates can be prepared without phosgene (see 10-21) by phase-transfer catalyzed treatment of primary alkyl halides with dry KHCO3 and K2C03- ... [Pg.489]

See other pages where Group 12 halides reaction with, phosgene is mentioned: [Pg.80]    [Pg.218]    [Pg.108]    [Pg.346]    [Pg.109]    [Pg.110]    [Pg.391]    [Pg.1276]    [Pg.391]    [Pg.61]    [Pg.352]    [Pg.356]    [Pg.362]    [Pg.362]    [Pg.362]    [Pg.363]    [Pg.363]    [Pg.61]    [Pg.843]    [Pg.246]    [Pg.46]    [Pg.292]   
See also in sourсe #XX -- [ Pg.342 ]



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With phosgene

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