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Group 14 elements silyl cations

The tricoordinate radicals of the heavier group 14 elements can be generated in one of the following ways (1) by the photolysis or thermolysis of the corresponding hydrides R3EH (E = heavier group 14 element) in the presence of the radical initiators, (2) by the y-irradiation of R4E or photolysis of RsE-Hg-ERs, or (3) by the thermolysis or photolysis of either R3E-ER3 or R3E-ER2-ER3 (4), (4) one-electron reduction of silicon cation (5), (5) one-electron oxidation of silyl anion (6), as well as by (6) one-electron reduction of alkylhalogenide (7). [Pg.37]

See other pages where Group 14 elements silyl cations is mentioned: [Pg.78]    [Pg.54]    [Pg.60]    [Pg.634]    [Pg.634]    [Pg.74]    [Pg.74]    [Pg.843]    [Pg.88]    [Pg.106]    [Pg.159]    [Pg.167]    [Pg.207]    [Pg.904]    [Pg.159]    [Pg.167]    [Pg.207]    [Pg.117]    [Pg.12]    [Pg.53]    [Pg.94]    [Pg.628]    [Pg.14]   


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Elements cations

Group-0 cations

Silyl cation

Silyl groups

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