Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Group algebraic representation of the antisymmetrizer

As we have seen in Eq. (5.21), an element of the group may be written as a sum over the algebra basis. For the symmetric groups, this takes the form, [Pg.80]

We wish to apply permutations, and the antisymmetrizer to products of spin-orbitals that provide a basis for a variational calculation. If each of these represents a pure spin state, the function may be factored into a spatial and a spin part. Therefore, the whole product, 4, may be written as a product of a separate spatial function and a spin function. Each of these is, of course, a product of spatial or spin functions of the individual particles, [Pg.80]

In line with the last section we give a version of Eq. (5.89) using the non-orthogonal matrix basis. [Pg.80]


See other pages where Group algebraic representation of the antisymmetrizer is mentioned: [Pg.80]   


SEARCH



Algebra representation

Antisymmetric

Antisymmetrization

Group algebra

Group representation

Representation of the group

Representations, of groups

© 2024 chempedia.info