Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Grieco

In 1990 Grieco et ah introduced an interesting new medium for the Diels-Alder reaction a 5 molar... [Pg.10]

In 1990 Grieco introduced a 5 molar solution of lithium perchlorate as a new medium for the Diels-Alder reaction that is capable of inducing not only an improvement of the rate but also of the endo-... [Pg.11]

Likewise, Grieco, while working with amphiphile-like reactants, observed an enhanced preference for endo-adduct in aqueous solutions, which he attributed to orientational effects within the micelles that were presumed to be present in the reaction mixture ". Although under the conditions used by Grieco, the presence of aggregates cannot be excluded, other studies have clearly demonstrated that micelle formation is not the reason for the improved selectivities . Micellar a peg tes even tend to diminish the preference for endo adduct. ... [Pg.25]

A few years after the first articles of Breslow had appeared, Grieco elegantly demonstrated that the astonishing rate and selectivity enhancements of Diels-Alder reactions in water can be exploited sirccessfully in organic synthesis. He extensively studied the reactivity of dienes containing... [Pg.27]

Grieco , Lubineau and Gajewski . Desimoni has observed linear correlations of the rate of the... [Pg.27]

Dramatic rate accelerations of [4 + 2]cycloadditions were observed in an inert, extremely polar solvent, namely in5 M solutions oflithium perchlorate in diethyl ether(s 532 g LiC104 per litre ). Diels-Alder additions requiring several days, 10—20 kbar of pressure, and/ or elevated temperatures in apolar solvents are achieved in high yields in some hours at ambient pressure and temperature in this solvent (P.A. Grieco, 1990). Also several other reactions, e.g, allylic rearrangements and Michael additions, can be drastically accelerated by this magic solvent. The diastereoselectivities of the reactions in apolar solvents and in LiClO EtjO are often different or even complementary and become thus steerable. [Pg.86]


See other pages where Grieco is mentioned: [Pg.2]    [Pg.10]    [Pg.10]    [Pg.11]    [Pg.19]    [Pg.33]    [Pg.36]    [Pg.36]    [Pg.37]    [Pg.40]    [Pg.40]    [Pg.41]    [Pg.41]    [Pg.41]    [Pg.42]    [Pg.48]    [Pg.70]    [Pg.70]    [Pg.73]    [Pg.73]    [Pg.108]    [Pg.123]    [Pg.131]    [Pg.363]    [Pg.421]    [Pg.109]    [Pg.91]    [Pg.328]    [Pg.230]    [Pg.245]    [Pg.452]    [Pg.212]    [Pg.17]    [Pg.17]    [Pg.33]    [Pg.80]    [Pg.126]    [Pg.189]    [Pg.194]    [Pg.194]    [Pg.195]    [Pg.195]    [Pg.272]    [Pg.404]   
See also in sourсe #XX -- [ Pg.159 ]

See also in sourсe #XX -- [ Pg.53 ]

See also in sourсe #XX -- [ Pg.85 ]




SEARCH



GRIECO Reagent

Grieco elimination

Grieco method, oxidation

Grieco reactions

Grieco three-component condensation

Grieco-Sharpless elimination

© 2024 chempedia.info