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Graham’s law of effusion The rate

This observation is now known as Graham s law of effusion. The rate of effusion is proportional to the average speed of the molecules in the gas because the average speed of the molecules determines the rate at which they approach the hole. Therefore, we can conclude that... [Pg.281]

Graham s law of effusion The rate of effusion of a gas is inversely proportional to the square root of its molar mass. [Pg.952]

Glycoside linkage a C—O—C bond formed between the rings of two cyclic monosaccharides by the elimination of water. (22.6) Graham s law of effusion the rate of effusion of a gas is inversely proportional to the square root of the mass of its particles. (5.7) Greenhouse effect a warming effect exerted by the earth s atmosphere (particularly COj and H2O) due to thermal energy retained by absorption of infrared radiation. (6.5)... [Pg.1087]

This relation is Graham s law of effusion the ratio of the rates of effusion of two gases, at the same P and T, are inversely proportional to the square roots of their molar masses. [Pg.54]

According to Graham s law of effusion, the effusion rate of a gas is inversely related to the square root of the molecular weight of the gas. This is true provided that we have the same pressure and temperature conditions. Graham s law can be expressed as shown below ... [Pg.85]

The enrichment procedure uses the small mass difference between the hexafluorides of uranium-235 and uranium-238 to separate them. The first procedure to be developed converts the uranium into uranium hexafluoride, UFfl, which can be vaporized readily. The different effusion rates of the two isotopic fluorides are then used to separate them. From Graham s law of effusion (rare of effusion l/(molar mass)1/2 Section 4.9), the rates of effusion of 235UFfe (molar mass, 349.0 g-mol ) and 238UF6 (molar mass, 352.1 g-mol ) should be in the ratio... [Pg.841]

We can use Graham s law to determine the rate of effusion of an unknown gas knowing the rate of a known one or we can use it to determine the molecular mass of an unknown gas. For example, suppose you wanted to find the molar mass of an unknown gas. You measure its rate of effusion versus a known gas, H2. The rate of hydrogen effusion was 3.728 mL/s, while the rate of the unknown gas was 1.000 mL/s. The molar mass of H2 is 2.016 g/mol. Substituting into the Graham s law equation gives ... [Pg.87]

Effusion and diffusion are substantially the same process. Diffusion is movement of a substance from an area of higher concentration to an area of lower concentration. Effusion is the movement of a gas through a small opening. Graham s Law of Effusion states the rate of effusion is inversely proportional to the square root of the molecular mass. [Pg.146]

One ramification of Eq. (18) is Graham s law of effusion, which deals with the rate at which gaseous molecules pass through a small hole in the wall of their enclosure (effusion). According to Graham, the rate per unit concentration is proportional to velocity and, thus, directly proportional to the square root of the absolute temperature and inversely proportional to the square root of the molecular mass. [Pg.24]

The correct answer is (A). There is a quick way to solve this and also a long way. The quick way is to remember that Graham s law states that the rate of effusion is inversely proportional to the square root of the molar mass. You can see pretty quickly that the molar mass of methane is 4 times that of helium. The square root of 4 is 2, meaning that helium will diffuse two times faster than methane. The longer way is to actually set up the equation — = and solve for r2. [Pg.172]

D) Wrong Graham s law of effusion states that the rates of effusion are inversely related to the square root of the molar mass. This means that smaller particles will effuse more quickly than larger particles. All three balloons will get smaller at different rates, which means they will be different sizes on the next day (hydrogen will be smallest, followed by helium, and then sulfur hexafluoride). [Pg.174]

Graham s law of effusion states that the rate at which a gas effuses is inversely proportional to the molecular weight of the gas. [Pg.176]

Graham s Law of Effusion states that at the same temperature and pressure, gases diffuse at a rate inversely proportional to the square roots of their molecular masses. What this translates to is that lighter (less dense) gases travel faster than heavier (more dense) gases. [Pg.34]

You are given the molar masses for ammonia and hydrogen chloride. To find the ratio of the diffusion rates for ammonia and hydrogen chloride, use the equation for Graham s law of effusion. [Pg.388]

The Process of Effusion One of the early triumphs of the kinetic-molecular theory was an explanation of effusion, the process by which a gas escapes from its container through a tiny hole into an evacuated space. In 1846, Thomas Graham studied this process and concluded that the effusion rate was inversely proportional to the square root of the gas density. The effusion rate is the number of moles (or molecules) of gas effusing per unit time. Because density is directly proportional to molar mass, we can state Graham s law of effusion as follows the rate of effusion of a gas is inversely proportional to the square root of its molar mass,... [Pg.164]

The relative rates of effusion of the two gases will allow the calculation of the mole fraction of each gas as it passes through the orifice. Using Graham s law of effusion,... [Pg.157]


See other pages where Graham’s law of effusion The rate is mentioned: [Pg.1095]    [Pg.215]    [Pg.1095]    [Pg.215]    [Pg.81]    [Pg.81]    [Pg.82]    [Pg.82]    [Pg.164]    [Pg.387]    [Pg.394]    [Pg.394]    [Pg.174]    [Pg.81]    [Pg.839]    [Pg.404]   


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