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Grafting reactions, porous silica

The second strategy is based on postsynthetic functionalization of a preexisting inorganic matrix. Mn(salen)-type complexes were covalently grafted onto the hybrid functionalized surface of porous silica (MCM-41) by reaction with vinyl substituted Schiff bases." ... [Pg.3298]

Figure 3.2.1 Si CP-MAS NMR spectra of non-porous Biosepra 100 silica (a) before grafting (b) after reaction with la. Q siloxane group Si(Oo.5)4 Q single hydroxyl silanol group SifOo.sIsOH double hydroxyl silanol group Si(Oo.s)2(OH)2... Figure 3.2.1 Si CP-MAS NMR spectra of non-porous Biosepra 100 silica (a) before grafting (b) after reaction with la. Q siloxane group Si(Oo.5)4 Q single hydroxyl silanol group SifOo.sIsOH double hydroxyl silanol group Si(Oo.s)2(OH)2...

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