Graft copolymer aminolysis

Acenaphthalene 119-122, 128, 134 Acrylates, activated 1, 3 -, reactivity ratios 7 -, -, suspension copolymerization 13 Acrylic groups 49, 53 A-Acryloxy derivatives 37 Active ester method, graft copolymers 29 Alkyl esters, aminolysis 14 Aminolysis, alkyl esters 14 Amphigels, polymer-solvent compatibility 24... 

Ogata et al. published several applications with graft copolymers of poly(7 benzyl-L-glutamate) onto suspension polymerized crosslinked polystyrene beads containing aminomethyl functions [39] (Scheme 6). 4- 7 7 3 benzyl ester group of the polypeptide side chain was converted either to benzyl amide by aminolysis or to free acid by hydrolysis and the effects... 

Scheme 5 Synthesis of highly pure block copolymers by combination of RAFT polymerization, azide-alkyne click reaction, and de-grafting, in which cleavage of grafted chains from a silica surface can be achieved by either aminolysis or radical-induced addition-fragmentation reactions (RIAFR). Adapted from Zhao et al. [20]...

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